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21.
研究了氯化镧对镁合金疏水膜耐蚀性的影响。采用中性盐雾试验和电化学试验测试了疏水膜的耐蚀性,并采用扫描电子显微镜观察了疏水膜的表面形貌。结果表明:氯化镧对镁合金疏水膜有一定的改性作用,使膜层由乳突状结构转变为层片状结构,进而使膜层由疏水表面转变为超疏水表面,其接触角可达153°。另外,添加氯化镧后疏水膜的盐雾时间延长至109.0 h,耐蚀性大幅提高。 相似文献
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Caio Felippe Curitiba Marcellos Camila M. Senna Figueiredo Frederico W. Tavares Maurício Bezerra de Souza Jr. Paulo Laranjeira da Cunha Lage João Francisco Cajaiba da Silva Argimiro R. Secchi Amaro G. Barreto Jr. 《加拿大化工杂志》2020,98(11):2435-2450
An experimental methodology for inferring brine dissolution rate in monoethylene glycol (MEG) solutions at different temperatures using a webcam combined with a mathematical model is presented. The measurement system is designed to track the RGB (red, green, and blue) colour variations during the dissolution process. A dynamic model augmented with the population balance equation is applied to describe the dissolution process. Moreover, the dissolution rate is consistently related to the temperature and MEG concentration through the driving force based on the Gibbs energy and chemical affinity. The applied low-cost measurement apparatus proved to be a useful resource for tracking the dissolution dynamics in a wide range of undersaturation. 相似文献
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This DFG-funded research project aimed to gain a better understanding of the mechanisms of the W-Cl repair principle within the framework of fundamental investigations, to contribute to the creation of the necessary basis for a broader application of the repair principle in practice. The focus was on the development of a model to describe the chloride redistribution after the application of a system sealing surface protective coating. On the basis of Fick's second law of diffusion, a mathematical model with a self-contained analytical solution was developed, with the help of which the chloride redistribution after application of a system sealing surface protective coating can be calculated under the idealized assumption of complete water saturation of the concrete. Furthermore, the influence of the dehydration of the concrete, expected as a result of the application of the repair principle W-Cl, on the chloride redistribution was investigated. On the basis of laboratory tests and numerical simulations, material-specific reduction functions were developed to quantify the relationship between the chloride diffusion coefficient and the ambient humidity. 相似文献
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为探讨能源消费结构调节下异质性环境规制对绿色全要素生产率的影响机制,论文利用SBM方向距离函数测得全国各省市“经济-资源-环境-社会”四位一体的绿色全要素生产率,并将环境规制工具分为命令控制型、经济激励型、治理投入型和公众参与型4类,构建了空间杜宾模型以及门槛效应模型,进而得出在能源消费结构调节下,异质性环境规制对绿色全要素生产率的直接作用、间接作用以及空间溢出效应。研究结果表明:1)经济激励型和公众参与型环境规制通过调节能源消费结构对当地和邻地的绿色全要素生产率产生影响;2)在门槛检验方面,能源消费结构对命令控制型、经济激励型和公众参与型环境规制影响绿色全要素生产率存在门槛效应,同时在能源消费结构调节下,命令控制型和经济激励型环境规制对其本身对绿色全要素生产率的间接作用存在门槛效应。建议政府在制定环境规制时要考虑到其与能源消费结构的交互作用,并且在不同能源消费水平地区采用适宜的规制方法和强度,以更好地发挥环境规制作用。 相似文献
25.
《能源学会志》2020,93(6):2362-2370
To facilitate the reuse and recycling of polyvinyl chloride (PVC) to achieve sustainable development and new industrialization, the composition and mechanism of formation of volatiles during the flash pyrolysis of PVC were studied by thermogravimetry-Fourier transform infrared (TG-FTIR) and pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS). TG and derivative thermogravimetry (DTG) analyses indicated two main degradation stages during flash pyrolysis of PVC, namely dehydrochlorination of PVC and decomposition of dechlorinated-PVC. Simultaneously, the FTIR results revealed that the main functional groups in the pyrolysis process were H–Cl, -C-Cl, C–H, CH, and aromatic groups. The relative content of main volatiles was determined by Py-GC/MS, and decreased in the following order: aromatics > alkenes > hydrogen chloride (HCl) > chlorinated hydrocarbons. Specifically, the relative content of aromatics was as high as 76.790–81.809%, while that of HCl was in the range of 3.016–3.096%. The carbon number distribution and the relative content of main products obtained from the flash pyrolysis of PVC at different final temperatures were also analysed. According to the experimental results, the mechanism of formation of the main volatiles based on free-radical reactions was deduced in detail. Therefore, this study provides further details for deepening the understanding of the PVC pyrolysis process. 相似文献
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干扰噪声直接影响局部放电法有效检测矿用高压电缆故障。基于局部放电法,综合采用理论计算、仿真实验、现场试验的方法,对比分析了短时傅里叶变换和傅里叶分析去噪法的原理和优缺点,提出了一种矿用高压电缆的局部放电去噪算法——小波阈值去噪法,同时,选择了合理的阈值函数和去噪流程。基于此,采用白噪声和连续周期信号作为高压电缆的干扰噪声,进行了模拟仿真实验。结果表明,小波阈值去噪法可有效抑制白噪声,其中,Db2小波性能和去噪效果最好;同时,现场试验结果显示,去噪后信噪比得到了显著增加,验证了小波阈值去噪法的合理性和可靠性。 相似文献
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Noise detection and its removal is very important in the image processing. Detection of noise is very crucial and significant in random valued impulse noise because it does not hamper the image pixels uniformly. This paper presents a novel and unique concept of adaptive dual threshold for the detection of random valued impulse noise along with simple median filter at noise removal stage. Simulation results shows that an efficient noise detection leads to a superior quality of de-noised image as compared to existing adaptive threshold based image de-noising techniques. Proposed threshold computation is based on averaging of pixel values of window which enhances the PSNR of our system as compared to existing median filter based image de-noising methods. 相似文献